Effect of different acidic fractions in crude oil on dynamic interfacial tensions in... Zhang, Lu; Luo, Lan; Zhao, Sui; Xu, Zhi-cheng; An, Jing-yi; Yu, Jia-yong 2004-01-01 00:00:00 Experimental studies have been performed with the intention to elucidate the mechanisms liable for synergism/antagonism for decreasing dynamic interfacial tension (IFT) in surfactant/alkali/acidic fraction mannequin oil systems. The dynamic interfacial tensions of different acidic fractions have been measured towards alkaline and/or surfactant solutions. The relationships between structure and interfacial tensions have been studied. We've found that the acid fractions with the lower common molecular weight ( M n 500) have appreciable aromaticity in the R side chain and present lower interfacial actions with alkaline options. The acidic fractions in oil part can influence the partition of added surfactants between the oil phase and aqueous section, which resulted within the change of interfacial tensions. The acidic fractions with the higher average molecular weight, which have excessive polarity, influenced interfacial tensions extra intensively. The synergism in decreasing interfacial tension in acidic fraction model oil/petroleum sulfonate systems and acidic fraction mannequin oil/alkali/petroleum sulfonate methods could be positive or damaging in line with the character of oil section and aqueous section. The EACN values of various model oils have been measured by utilizing petroleum sulfonate mixtures with varied n min values. We've found that antagonism was noticed usually when EACN/ n min worth was far from unity, while synergism was observed when EACN/ n min value was near unity.

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